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Even after the present form of yttrium vanadate phosphor had been introduced for mercury lamps in the late 1960's, much work continued in finding still more efficient phosphor blends which could deliver lamps with warmer colour temperatures.
In general two different lines of research were followed, to create either lamps having better colour rendering properties, or lamps delivering a higher luminous flux. The types with increased luminous efficacy comprised orthophosphate type materials, which added green light to the spectrum and to which the eye is particularly sensitive. Colour rendering left rather a lot to be desired though!
The initial types with improved colour were realised through developments in materials such as yttrium borate, which has enhanced red emission. However, lamps with such materials have rather poor luminous efficacies.
Philips aimed to overcome this issue by using the newer red-enhanced phosphors in combination with others which contributed to the orange part of the spectrum. The result was the HPL-Comfort lamp, which has both a lower colour temperature and a higher efficacy. Crucially its chromaticity lies on the blackbody locus so the light output is a good white.
The phosphor blend in this lamp is believed to comprise yttrium phosphate-vanadate plus a cerium activated YAG phosphor. The latter material is stimulated by blue light rather than UV, the blue absorption being responsible for the slight yellowish appearance of this lamp. Ordinarily YAG phosphors generate green light but on account of the high bulb wall temperature its output is shifted to orange here.
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